Acta Crystallographica Section E (Aug 2009)

Tris(1H-imidazole-κN3)(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ3O2,O3,O7)cobalt(II) 3.35-hydrate

  • Jian-Ping Cheng,
  • Qiu-Yue Lin,
  • Rui-Ding Hu,
  • Yan-Jun Wang

DOI
https://doi.org/10.1107/S1600536809024039
Journal volume & issue
Vol. 65, no. 8
pp. m854 – m854

Abstract

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In the crystal structure of the title compound, [Co(C8H8O5)(C3H4N2)3]·3.35H2O, the central CoII ion is in a slightly distorted octahedral environment, coordinated by the bridging O atom from the bicyclo[2.2.1]heptane ligand, by two carboxylate O atoms from two different carboxylate groups and by three N atoms from imidazole ligands. Uncoordinated water molecules, some of them disordered, are present in the crystal structure. In the crystal structure, molecules are linked by O—H...O, N—H...O and O—H...N hydrogen-bonding interactions.