Improvement of Mechanical Properties and Solvent Resistance of Polyurethane Coating by Chemical Grafting of Graphene Oxide

Guotao Liang; Fengbiao Yao; Yanran Qi; Ruizhi Gong; Rui Li; Baoxuan Liu; Yueying Zhao; Chenglong Lian; Luming Li; Xiaoying Dong; Yongfeng Li

doi:10.3390/polym15040882

Polymers (Feb 2023)

Improvement of Mechanical Properties and Solvent Resistance of Polyurethane Coating by Chemical Grafting of Graphene Oxide

Guotao Liang,
Fengbiao Yao,
Yanran Qi,
Ruizhi Gong,
Rui Li,
Baoxuan Liu,
Yueying Zhao,
Chenglong Lian,
Luming Li,
Xiaoying Dong,
Yongfeng Li

Affiliations

Guotao Liang: State Forestry and Grassland Administration Key Laboratory of Silviculture in Down-Stream Areas of the Yellow River, College of Forestry, Shandong Agricultural University, Tai’an 271018, China
Fengbiao Yao: State Forestry and Grassland Administration Key Laboratory of Silviculture in Down-Stream Areas of the Yellow River, College of Forestry, Shandong Agricultural University, Tai’an 271018, China
Yanran Qi: State Forestry and Grassland Administration Key Laboratory of Silviculture in Down-Stream Areas of the Yellow River, College of Forestry, Shandong Agricultural University, Tai’an 271018, China
Ruizhi Gong: State Forestry and Grassland Administration Key Laboratory of Silviculture in Down-Stream Areas of the Yellow River, College of Forestry, Shandong Agricultural University, Tai’an 271018, China
Rui Li: School of Automation, Chongqing University of Posts and Telecommunications, Chongqing 400065, China
Baoxuan Liu: Shandong Laucork Development Co., Ltd., Jining 272100, China
Yueying Zhao: Postdoctoral Innovation Practice Base, Shandong Xiaguang Group Co., Ltd., Jining 277600, China
Chenglong Lian: State Forestry and Grassland Administration Key Laboratory of Silviculture in Down-Stream Areas of the Yellow River, College of Forestry, Shandong Agricultural University, Tai’an 271018, China
Luming Li: College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China
Xiaoying Dong: State Forestry and Grassland Administration Key Laboratory of Silviculture in Down-Stream Areas of the Yellow River, College of Forestry, Shandong Agricultural University, Tai’an 271018, China
Yongfeng Li: State Forestry and Grassland Administration Key Laboratory of Silviculture in Down-Stream Areas of the Yellow River, College of Forestry, Shandong Agricultural University, Tai’an 271018, China

DOI: https://doi.org/10.3390/polym15040882
Journal volume & issue: Vol. 15, no. 4
p. 882

Abstract

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Waterborne polyurethane coatings (WPU) are widely used in various types of coatings due to their environmental friendliness, rich gloss, and strong adhesion. However, their inferior mechanical properties and solvent resistance limit their application on the surface of wood products. In this study, graphene oxide (GO) with nanoscale size, large surface area, and abundant functional groups was incorporated into WPU by chemical grafting to improve the dispersion of GO in WPU, resulting in excellent mechanical properties and solvent resistance of WPU coatings. GO with abundant oxygen-containing functional groups and nanoscale size was prepared, and maintained good compatibility with WPU. When the GO concentration was 0.7 wt%, the tensile strength of GO-modified WPU coating film increased by 64.89%, and the abrasion resistance and pendulum hardness increased by 28.19% and 15.87%, respectively. In addition, GO also improved the solvent resistance of WPU coatings. The chemical grafting strategy employed in this study provides a feasible way to improve the dispersion of GO in WPU and provides a useful reference for the modification of waterborne wood coatings.

Published in Polymers

ISSN: 2073-4360 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.mdpi.com/journal/polymers/

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