Minerals (Jun 2024)
Mineralogy and Geochemistry of Jasperoid Veins in Neoproterozoic Metavolcanics: Evidence of Silicification, Pyritization and Hematization
Abstract
The Wadi Ranga sulfidic jasperoids in the Southern Eastern Desert (SED) of Egypt are hosted within the Neoproterozoic Shadli metavolcanics as an important juvenile crustal section of the Arabian Nubian Shield (ANS). This study deals with remote sensing and geochemical data to understand the mechanism and source of pyritization, silicification, and hematization in the host metavolcanics and to shed light on the genesis of their jasperoids. The host rocks are mainly dacitic to rhyolitic metatuffs, which are proximal to volcanic vents. They show peraluminous calc-alkaline affinity. These felsic metatuffs also exhibit a nearly flat REE pattern with slight LREE enrichment (La/Yb = 1.19–1.25) that has a nearly negative Eu anomaly (Eu/Eu* = 0.708–0.776), while their spider patterns display enrichment in Ba, K, and Pb and depletion in Nb, Ta, P, and Ti, reflecting the role of slab-derived fluid metasomatism during their formation in the island arc setting. The ratios of La/Yb (1.19–1.25) and La/Gd (1.0–1.17) of the studied felsic metatuffs are similar to those of the primitive mantle, suggesting their generation from fractionated melts that were derived from a depleted mantle source. Their Nb and Ti negative anomalies, along with the positive anomalies at Pb, K, Rb, and Ba, are attributed to the influence of fluids/melt derived from the subducted slab. The Wadi Ranga jasperoids are mainly composed of SiO2 (89.73–90.35 wt.%) and show wide ranges of Fe2O3t (2.73–6.63 wt.%) attributed to the significant amount of pyrite (up to 10 vol.%), hematite, goethite, and magnetite. They are also rich in some base metals (Cu + Pb + Zn = 58.32–240.68 ppm), leading to sulfidic jasperoids. Pyrite crystals with a minor concentration of Ag (up to 0.32 wt.%) are partially to completely converted to secondary hematite and goethite, giving the red ochre and forming hematization. Euhedral cubic pyrite is of magmatic origin and was formed in the early stages and accumulated in jasperoid by epigenetic Si-rich magmatic-derived hydrothermal fluids; pyritization is considered a magmatic–hydrothermal stage, followed by silicification and then hematization as post-magmatic stages. The euhedral apatite crystals in jasperoid are used to estimate the saturation temperature of their crystallization from the melt at about 850 °C. The chondrite (C1)-normalized REE pattern of the jasperoids shows slightly U–shaped patterns with a slightly negative Eu anomaly (Eu/Eu* = 0.43–0.98) due to slab-derived fluid metasomatism during their origin; these jasperoids are also rich in LILEs (e.g., K, Pb, and Sr) and depleted in HFSEs (e.g., Nb and Ta), reflecting their hydrothermal origin in the island arc tectonic setting. The source of silica in the studied jasperoids is likely derived from the felsic dyke and a nearby volcanic vent, where the resultant Si-rich fluids may circulate along the NW–SE, NE–SW, and E–W major faults and shear zones in the surrounding metavolcanics to leach Fe, S, and Si to form hydrothermal jasperoid lenses and veins.
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