Acta Crystallographica Section E (Aug 2012)

1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)methyl]benzene

  • Lara C. Spencer,
  • Ilia A. Guzei,
  • Tebogo V. Segapelo,
  • James Darkwa

DOI
https://doi.org/10.1107/S1600536812032801
Journal volume & issue
Vol. 68, no. 8
pp. o2584 – o2584

Abstract

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The title compound, C38H30N4, a potentially mono- and bidentate ligand, does not seem to form palladium complexes similar to other poly(pyrazol-1-ylmethyl)benzenes due to the large steric size of the phenyl substituents on the pyrazole rings. The pyrazole rings have a 21.09 (5)° angle between their mean planes and exhibit a trans-like geometry in which the in-plane lone pairs of electrons on the 2-N nitrogen atoms point in opposite directions.