IUCrData (Nov 2016)

Diisopropylammonium (3,6-dichlorobenzene-1,2-dithiolato)cuprato(III) tetrahydrofuran monosolvate

  • Jesús Barrio,
  • Esther Delgado,
  • Diego Hernández,
  • Elisa Hernández,
  • Josefina Perles,
  • Félix Zamora

DOI
https://doi.org/10.1107/S2414314616018836
Journal volume & issue
Vol. 1, no. 11
p. x161883

Abstract

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The asymmetric unit of the title compound, (C6H16N)[Cu(C6H2Cl2S2)2]·C4H8O, comprises a [Cu(SC6H2Cl2S)2]− anion, an [iPr2NH2]+ cation and a solvent tetrahydrofuran molecule. The CuIII atom has an almost square-planar CuS4 coordination environment. In the crystal, the anion and the solvent molecule are linked via N—H...O and N—H...S hydrogen bonds involving the diisopropylammonium cation. There are no other significant intermolecular interactions present.

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