Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximes

Bao Gui Cai; Qian Li; Lei Li; Jun Xuan

Green Synthesis and Catalysis (May 2022)

Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximes

Bao Gui Cai,
Qian Li,
Lei Li,
Jun Xuan

Affiliations

Bao Gui Cai: Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China
Qian Li: Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China
Lei Li: Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China
Jun Xuan: Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China; Key Laboratory of Structure and Functional Regulation of Hybrid Materials (Anhui University), Ministry of Education, Hefei 230601, China; Corresponding author. Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China.

Journal volume & issue: Vol. 3, no. 2
pp. 194 – 197

Abstract

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Visible light promoted C–O bond formation reaction through O–H insertion of acylsilanes with oximes has been developed. The reaction occurred under mild reaction conditions (sole blue LED irradiation in the absence of any catalysts or additives) with a short reaction time and afforded the corresponding oxime ethers in moderate to good yields.

Published in Green Synthesis and Catalysis

ISSN: 2666-5549 (Online)
Publisher: KeAi Communications Co. Ltd.
Country of publisher: China
LCC subjects: Technology: Chemical technology; Science: Chemistry: Organic chemistry: Biochemistry
Website: https://www.keaipublishing.com/en/journals/green-synthesis-and-catalysis/

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