Indonesian Journal of Chemistry (Mar 2016)

Isothermal Vapor-Liquid Equilibrium of Methanol + Glycerol and 1-Propanol + Glycerol

  • Annas Wiguno,
  • Asalil Mustain,
  • Wahyu Fazar Eka Irwansyah,
  • Gede Wibawa

DOI
https://doi.org/10.22146/ijc.21186
Journal volume & issue
Vol. 16, no. 1
pp. 111 – 116

Abstract

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Isothermal vapor-liquid equilibrium (VLE) data for two binary mixtures of methanol + glycerol and 1-propanol + glycerol were determined at the temperature range from (313.15 to 363.15) K using a simple quasi-static ebulliometer. All systems showed that the vapor pressures increased with increasing alcohols (methanol or 1-propanol) concentrations at corresponding system. The Wilson, Non-Random Two-Liquid (NRTL) and Universal Quasi-Chemical (UNIQUAC) activity coefficient models were used to correlate the experimental data. Both systems showed slightly deviations from the ideal liquid phase behavior.

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