Acta Crystallographica Section E (Aug 2010)

Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-κ2N1,O)rhenate(I)

  • Janine Suthiram,
  • Jan Rijn Zeevaart,
  • Hendrik G. Visser,
  • Andreas Roodt

DOI
https://doi.org/10.1107/S160053681002893X
Journal volume & issue
Vol. 66, no. 8
pp. m1042 – m1043

Abstract

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In the title compound, (C8H20N)[Re(C9H5N2O2)Cl(CO)3], the ReI atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C—H...O hydrogen bonding and π–π stacking interactions involving the benzene rings, with a centroid–centroid distance of 3.4220 (1) Å.