Hydroxylation of Phenol over M-MCM-48

Ch. Subrahmanyam; B. Louis; B. Viswanathan; A. Renken; T.K. Varadarajan

doi:10.18321/ectj418

Eurasian Chemico-Technological Journal (Mar 2001)

Hydroxylation of Phenol over M-MCM-48

Ch. Subrahmanyam,
B. Louis,
B. Viswanathan,
A. Renken,
T.K. Varadarajan

Affiliations

Ch. Subrahmanyam: Department of Chemistry, Indian Institute of Technology Madras, Chennai-600 036, India
B. Louis: Institute of Chemical Engineering, Swiss Federal Institute of Technology, CH-1015 Lausanne, Switzerland
B. Viswanathan: Department of Chemistry, Indian Institute of Technology Madras, Chennai-600 036, India
A. Renken: Institute of Chemical Engineering, Swiss Federal Institute of Technology, CH-1015 Lausanne, Switzerland
T.K. Varadarajan: Department of Chemistry, Indian Institute of Technology Madras, Chennai-600 036, India

DOI: https://doi.org/10.18321/ectj418
Journal volume & issue: Vol. 3, no. 1
pp. 59 – 63

Abstract

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The synthesis and characterization of M-MCM-48 (M= Si, Ti, V, Cr and Mn) materials have been carried out. These systems promote hydroxylation of phenol with 30 % H2O2 and the hydroxylation activity is highest for Ti-MCM-48. Water appears to be a better solvent than acetone and acetonitrile.

Published in Eurasian Chemico-Technological Journal

ISSN: 1562-3920 (Print); 2522-4867 (Online)
Publisher: al-Farabi Kazakh National University
Country of publisher: Kazakhstan
LCC subjects: Science: Chemistry
Website: http://ect-journal.kz

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