Exploring Humic Acid as an Efficient and Selective Adsorbent for Lead Removal in Multi-Metal Coexistence Systems: A Review

Abstract

Water pollution poses a global threat to human health, particularly in terms of ensuring a safe supply of drinking water. The accumulation of heavy metals from various water sources is increasing, driving the search for effective and environmentally friendly approaches and materials for metal removal. This review investigates the selective adsorption of Pb2+ by humic acid (HA) in a multi-metal coexistence solution. The focus is on discussing approaches to the structural identification of HA, highlighting that separation techniques are an effective method to reduce its heterogeneity. Starting from the key structural units of HA, the study reveals the interaction between HA and heavy metals. Approaches to enhance Pb2+ selective adsorption are explored, proposing that introducing activating groups, Ca ion exchange, and optimizing pore structures are effective approaches for improving lead ion selective adsorption. Ca2+ activation is suggested as a future research direction for lead-selective adsorption. Additionally, attaining lead selective adsorption through pH regulation’s significance is emphasized. This research contributes to a fundamental understanding of HA’s role as a selective lead adsorbent while offering practical implications for developing environmentally friendly adsorbent materials. The results aim to advance knowledge in environmental science and water treatment.

Keywords

• humic acid
• fractionation
• structural identification
• selective adsorption
• modification method