Effect of alumina addition on the phase transformation and crystallisation properties of refractory cordierite prepared from amorphous rice husk silica

Abstract

The effect of alumina addition of 5–30% by weight on phase transformation and crystallisation properties of refractory cordierite ceramics prepared from amorphous rice husk silica followed by sintering treatment at temperature of 1230 °C was studied. The crystallinity and microstructure of the samples were characterised using X-ray diffraction (XRD) coupled with Rietveld analysis, scanning electron microscopy (SEM), respectively. Some physical properties include density, porosity, hardness, bending strength, and thermal expansion coefficient of the samples with different alumina additions were measured. The results show that addition of alumina promoted crystallisation of cordierite into crystalline spinel, corundum, cristobalite, in which with addition of 10–30% alumina, the cordierite phase was practically undetected. Addition of alumina was also found to increase the amount of spinel, while corundum and cristobalite decreased following alumina addition of 10–30%. The presence of spinel, corundum, and cristobalite resulted in increased of density, hardness, bending strength and thermal expansion coefficient, while for porosity, the opposite was observed. Thermal expansion coefficient of the samples with alumina addition of 15–30% reach the relatively constant value of 9.5 × 10−6/°C, with the main crystalline phase was spinel, accompanied by corundum and cristobalite in smaller quantities.

Keywords

• Microstructure
• Composition
• Rice husk silica
• Structure
• Refractoriness