Acta Crystallographica Section E (Dec 2008)
[O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I)
Abstract
A nearly linear coordination geometry for Au is found in the title compound, [Au(C9H9N2O3S)(C21H21P)]. The thiocarbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au...π contact [Au...Cg = 3.351 (5) Å; Cg is the centroid of the aromatic ring].