Acta Crystallographica Section E (Dec 2008)

[O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I)

  • Edward R. T. Tiekink,
  • Grant A. Broker

DOI
https://doi.org/10.1107/S1600536808038257
Journal volume & issue
Vol. 64, no. 12
pp. m1582 – m1582

Abstract

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A nearly linear coordination geometry for Au is found in the title compound, [Au(C9H9N2O3S)(C21H21P)]. The thiocarbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au...π contact [Au...Cg = 3.351 (5) Å; Cg is the centroid of the aromatic ring].