Acta Crystallographica Section E (Jul 2013)

Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II)

  • Amitabha Datta,
  • Barbara Machura,
  • Jui-Hsien Huang,
  • Shiann-Cherng Sheu

DOI
https://doi.org/10.1107/S1600536813016188
Journal volume & issue
Vol. 69, no. 7
pp. m399 – m399

Abstract

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In the molecule of the title compound, [Ni(C19H20N2O4)(H2O)2], the central NiII ion lies on a mirror plane and is surrounded by an N2O4 coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atoms of the tetradentate Schiff base ligand. In the crystal, O—H...O hydrogen bonds between the water molecules and the phenolic and methoxy O atoms of neighbouring molecules lead to the formation of rods propagating parallel to [100].