Application of non-thermal plasma reactor for degradation and detoxification of high concentrations of dye Reactive Black 5 in water

Abstract

Degradation and detoxification efficiency of high concentrations of commercially available reactive textile dye Reactive Black 5 solution (40, 80, 200, 500, 1000 mg L-1), were studied. Advanced oxidation processes in water falling film based dielectric barrier discharge as a non-thermal plasma reactor were used. For the first time, this reactor was used for the treatment of high concentrations of organic pollutants such as reactive textile dye Reactive Black 5 in water. Solution of the dye is treated by plasma as thin water solution film that is constantly regenerated. Basically, the reactor works as a continuous flow reactor and the electrical discharge itself takes place at the gas-liquid interphase. The dye solution was recirculated through the reactor with an applied energy density of 0-374 kJ L-1. Decolorization efficiency (%) was monitored by UV-VIS spectrophotometric technique. Samples were taken after every recirculation (~ 22 kJ L-1) and decolorization percent was measured after 5 min and 24 h of plasma treatment. The efficiency of degradation (i.e. mineralization) and possible degradation products were also tracked by determination of the chemical oxygen demand (COD) and by ion chromatography (IC). Initial toxicity and toxicity of solutions after the treatment were studied with Artemia salina test organisms. Efficiency of decolorization decreased with the increase of the dye concentration. Complete decolorization, high mineralization and non-toxicity of the solution (<10 %) were acomplished after plasma treatment using energy density of 242 kJ L-1, while the initial concentrations of Reactive Black 5 were 40 and 80 mg L-1. [Projekat Ministarstva nauke Republike Srbije, br. 172030 i br. 171034]

Keywords

• reactive textile dyes
• decolorization
• plasma treatment
• dielectric barrier discharge reactor
• ecotoxicity