Acta Crystallographica Section E (Dec 2013)

2-[(Ferrocen-1-yl)(hydroxy)methyl]prop-2-enenitrile

  • R. Raghunathan,
  • S. Kathiravan,
  • K. Ravikumar,
  • S. Selvanayagam

DOI
https://doi.org/10.1107/S1600536813031218
Journal volume & issue
Vol. 69, no. 12
pp. m669 – m669

Abstract

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In the title ferrocene derivative, [Fe(C5H5)(C9H8NO)], the dihedral angle between the enenitrile group and the substituted cyclopentadienyl ring is 71.2 (1)°. The cyclopentadienyl rings of the ferrocene moiety are arranged in an eclipsed conformation. The hydroxy group, and the corresponding methine H atom, are disordered over two sets of sites with site-occupancy factors of 0.744 (4) and 0.256 (4). An intramolecular C—H...O close contact is observed. In the crystal, O—H...N hydrogen bonds form a C(6) chain along [100].