Acta Crystallographica Section E (Aug 2010)

trans-K3[TcO2(CN)4]

  • Sayandev Chatterjee,
  • Andrew S. Del Negro,
  • Matthew K. Edwards,
  • Brendan Twamley,
  • Jeanette A. Krause,
  • Samuel A. Bryan

DOI
https://doi.org/10.1107/S1600536810028205
Journal volume & issue
Vol. 66, no. 8
pp. i61 – i62

Abstract

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The structure of the title compound, tripotassium trans-tetracyanidodioxidotechnetate(V), is isotypic with its Re analogue. The [TcO2(CN)4]3− trans-tetracyanidodioxidotechnetate anion has a slightly distorted octahedral configuration. The Tc atom is located on a center of inversion and is bound to two O atoms in axial and to four cyanide ligands in equatorial positions. The Tc—O distance is consistent with a double-bond character. The two potassium cations, one located on a center of inversion and one in a general position, reside in octahedral or tetrahedral environments, respectively. K...O and K...N interactions occur in the 2.7877 (19)–2.8598 (15) Å range.