Effects of TiO2 on the mechanical and physical properties of Fe2O3-Doped Yttria-Stabilized Zirconia for electrolyte of Solid Oxide Fuel Cells

Abstract

Yttria-Stabilized Zirconia (YSZ) based electrolytes of Solid Oxide Fuel Cell (SOFC) are widely used due to their higher ionic conductivity, stability, and availability. The present study focuses on improving the performance of YSZ-based electrolytes particularly by doping other particles into YSZ. TiO2 was doped into Fe2O3-8YSZ composite and the effects of TiO2 on the mechanical and physical properties of the composites were observed. The concentrations of TiO2 were varied by 0 wt%, 1 wt%, 3 wt%, and 5 wt% for different compositions of the composites. The samples were fabricated by the solid-state reaction method by pressing the powders at 250 MPa for 3 min and were sintered at 1250 °C for 4 h. The sintered samples were then undergone through characterization tests in terms of percentage of volume shrinkage, density, porosity, Diametral Tensile Strength (DTS), and microhardness. The highest values of volume shrinkage (34.83%), relative density (97.83%), DTS (36.58 MPa), hardness (965 HV), and the lowest porosity (2.17%) were found for 5 wt% TiO2 addition. Besides, the lowest values of volume shrinkage (28.44%), relative density (87.94%), DTS (3.24 MPa), microhardness (340 HV), and the highest porosity (12.06%) were found for Fe2O3-8YSZ composites without (0 wt%) TiO2 addition.

Keywords

• Yttria-stabilized zirconia
• Electrolyte
• Solid oxide fuel cells
• TiO2 dopant
• Sintering