Acta Crystallographica Section E (Apr 2009)

Diaquabis(N,N-diethylnicotinamide-κN1)bis(4-formylbenzoato-κO)cobalt(II)

  • Mustafa Sertçelik,
  • Barış Tercan,
  • Ertan Şahin,
  • Hacali Necefoğlu,
  • Tuncer Hökelek

DOI
https://doi.org/10.1107/S1600536809008265
Journal volume & issue
Vol. 65, no. 4
pp. m389 – m390

Abstract

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In the crystal structure of the title CoII complex, [Co(C8H5O3)2(C10H14N2O)2(H2O)2], the metal centre is located on an inversion center and is coordinated by two 4-formylbenzoate (FOB), two diethylnicotinamide (DENA) ligands and two water molecules in a slightly distorted CoO4N2 octahedral geometry. In the crystal structure, O—H...O hydrogen bonds link the molecules into infinite chains. π–π contacts between the parallel pyridine rings of neighboring DENA ligands [centroid–centroid distance = 3.652 (3) Å] further stabilize the crystal structure.