Self-Assembly of Zinc Oxide Photonic Crystals in Viscous Liquids: Synthesis, Characterization, and Application to Colored Contact Lenses

Abstract

Structural color is a kind of natural color that widely exists in nature. The ordered microstructure of nano materials can absorb or reflect light of specific wavelength, thus showing colorful colors. Structural color is an ideal choice for color contact lens pattern pigment due to its good tinting degree, stability, and nontoxicity. This paper explores a method for synthesis of zinc oxide (ZnO) nanoparticles with a high refractive index and enhancement of the brightness of the structured colors by introducing carbon black nanoparticles. This method is convenient and successful to prepare ZnO ink, which can produce bright structural colors, and to produce color patterns through rubber pad printing. It is worth mentioning that ZnO nanoparticles can be self-assembled and arranged in contact lens ink without subsequent complicated processing. At the same time, the color only comes from ZnO and carbon black. While there is no other organic matter, the presence of nanoparticles plays a certain role in sterilization. Blue contact lenses prepared by this method have bright structural color, high oxygen permeability, and high hydrophilicity. At the same time, a cell viability test showed that the contact lenses prepared by this method had low adsorption capacity for lipids and proteins, reflecting the photonic crystal’s high biocompatibility. In summary, a trend for future research is to use high-refractive-index zinc oxide nanoparticles to produce structural colors rather than employing conventional contact lens pigments.

Keywords

• photonic crystal
• photon pigment
• viscous liquids
• zinc oxide
• contact lenses