Orbital: The Electronic Journal of Chemistry (Jan 2018)

Fluorescence Spectroscopy Applied in the Identification of Lubricant Oils

  • Claudio Yamamoto Morassuti,
  • Sandro Marcio Lima,
  • Fabio Alencar dos Santos,
  • Luis Humberto da Cunha Andrade

Journal volume & issue
Vol. 10, no. 1

Abstract

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In this work, we report the use of fluorescence spectroscopy to identify lubricant oils. Optical characterization was performed in four commercial lubricant oils that are used in reciprocating compressors. Mid-infrared absorption of samples indicates the presence of aromatic rings showing bands at 1605 cm-1 (C=C stretching) and 815 cm-1 (C–H stretch out of plane). UV-VIS absorption spectra show bands of di- and polyaromatic rings (around 230 nm and 260 nm, respectively). By exciting the samples at 360 nm, a broad emission band centered at 440 nm is observed, indicating that this excitation is appropriate to be used for the diagnosis of oil presence in the environment. DOI: http://dx.doi.org/10.17807/orbital.v10i1.1032

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