Hygienic quality of soil in the Gemer region (Slovakia) and the impact of risk elements contamination on cultivated agricultural products

Abstract

Abstract The Gemer region (Slovakia) belongs to areas with a high concentration of risk elements. The contents of Cu, Ni, Pb, Cd, Hg and Mn were determined in soils and cultivated agricultural production from lands in three cadastres of the Gemer region (Henckovce (48.713845, 20.426189) and Nižná Slaná (48.717373, 20.4208423), cultivated crop—spring triticale; Gemerská Poloma (48.704523, 20.487645), cultivated crop—maize). Bioavailable forms of Pb (0.306–0.532 mg/kg) and Cd (0.104–0.154 mg/kg), pseudototal forms of Cd (3.07–3.98 mg/kg) and Hg (0.484–2.18 mg/kg) represented the highest risk in soils. The highest contents of Pb (Cd, Hg) were in maize from Gemerská Poloma: 0.898 (0.081, 0.399) mg/kg DM. Soils were classified based on several indicators of soil contamination. The highest values of indicators are: Contamination factor (Cf 29.1—Hg), Degree of contamination (Cdeg 51.5), Potential ecological risk factor (Er 1163—Hg), Potential ecological risk index (RI 1,520), Pollution load index (PLI 4.76), Geo-accumulation index (Igeo 5.60—Hg). All indicators concerned the lands of Henckovce and Gemerská Poloma, RI also concerned the land of Nižná Slaná. Bioaccumulation factor (BAF) was calculated to assess the plant's ability to absorb the risk element. For both crops and all risk elements, BAF values were < 1. Obtained results indicate heavy metal contamination of soils, therefore monitoring of soils in investigated area is necessary.