Acta Crystallographica Section E (Dec 2008)

Sodium 2-iodobenzenesulfonate monohydrate

  • Waseeq Ahmad Siddiqui,
  • Muhammad Shafiq,
  • Islam Ullah Khan,
  • M. Nawaz Tahir,
  • Muhammad Nadeem Arshad

DOI
https://doi.org/10.1107/S1600536808039202
Journal volume & issue
Vol. 64, no. 12
pp. m1628 – m1628

Abstract

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In the title compound, Na+·C6H4IO3S−·H2O, the Na atom is hexacoordinated by O atoms, forming a two-dimensional sheet-like structure in the bc plane, with the iodobenzene rings protruding above and below. Na...O contact distances are in the range 2.419 (2)–2.7218 (18) Å and O...Na...O angles are in the range 73.70 (5)–158.64 (7)°. The crystal structure is stabilized by O—H...O and C—H...O hydrogen bonds and C—H...π interactions. The I atom is disordered over two positions with occupancies of 0.78 (2) and 0.22 (2).