Acta Crystallographica Section E (Oct 2013)

Dibromidobis(2-methyl-1H-benzimidazole-κN3)cadmium

  • Bao-Cheng Liu,
  • Yan-Ling Jin,
  • Fa-Qian Liu

DOI
https://doi.org/10.1107/S1600536813024549
Journal volume & issue
Vol. 69, no. 10
pp. m536 – m536

Abstract

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In the title compound, [CdBr2(C8H8N2)2], the CdII atom has a distorted tetrahedral coordination formed by the two imino N atoms of two 2-methylbenzimidazole ligands and two terminal bromide ligands. The CdII atom is slightly out of the benzimidazole planes by 0.320 (3) and 0.210 (3) Å. The dihedral angle between the benzimidazole planes is 71.6 (2)°. In the crystal, molecules are linked by N—H...Br hydrogen bonds into puckered layers parallel to (001).