A convenient and highly efficient catalytic oxidation of alcohol to acid using CoCl2-[Cemim]Br under mild conditions

Manickam Deepa; Selvarasu Uthayanila; Ramasamy Shanmuga Priya; Parasuraman Karthikeyan

Journal of Ionic Liquids (Jun 2022)

A convenient and highly efficient catalytic oxidation of alcohol to acid using CoCl2-[Cemim]Br under mild conditions

Manickam Deepa,
Selvarasu Uthayanila,
Ramasamy Shanmuga Priya,
Parasuraman Karthikeyan

Affiliations

Manickam Deepa: PG and Research Department of Chemistry Pachaiyappas College Campus, University of Madras Chennai, 600 030, Tamilnadu, INDIA
Selvarasu Uthayanila: Department of Chemistry, Pachaiyappas College for Women Campus, University of Madras, Kanchipuram, 631501 Tamilnadu, INDIA
Ramasamy Shanmuga Priya: PG and Research Department of Chemistry Pachaiyappas College Campus, University of Madras Chennai, 600 030, Tamilnadu, INDIA
Parasuraman Karthikeyan: PG and Research Department of Chemistry Pachaiyappas College Campus, University of Madras Chennai, 600 030, Tamilnadu, INDIA; Corresponding author.

Journal volume & issue: Vol. 2, no. 1
p. 100025

Abstract

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Herein we first reported on the CoCl2 supported ionic liquid [Cemim] Br-catalysed conversion of aliphatic and aromatic alcohol to acid using hydrogen peroxide as an oxidant. The oxidation reaction proceeded selectively with good yields in comparison to various other solvents. This method as appealing way for greener oxidation system includes mild reaction condition, short reaction time, less poisonous catalyst and oxidant under optimal condition give well to good yields.

Published in Journal of Ionic Liquids

ISSN: 2772-4220 (Online)
Publisher: Elsevier
Country of publisher: Netherlands
LCC subjects: Science: Chemistry
Website: https://www.journals.elsevier.com/journal-of-ionic-liquids

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