Interfacial bonding characteristics of multi-walled carbon nanotube/ultralight foamed concrete

Abstract

In the development of carbon nanotube (CNT)-reinforced cement-based matrices, one of the fundamental issues that investigators are confronting is CNT/cement-based matrix interfacial bonding, which determines the load transfer capability from the matrix to the CNT. In the present work, the stress transfer properties of multi-walled carbon nanotubes (MWCNTs) and ultralight foamed concrete matrices were studied using microscopic Raman spectrometry analysis. Two types of CNTs, such as MWCNT and MWCNT-COOH, were considered, wherein MWCNT-COOH was covered with fundamental COOH groups. The results show that the compressive and flexural strengths were 75 and 236% better for ultralight foamed concrete with a dry density of 200 kg/m3 with 0.4 wt% MWCNT-COOH addition, respectively. This indicates that the fundamental COOH groups of the MWCNT play an important role in determining the interfacial bonding characteristics between the MWCNT and the ultralight foamed concrete matrix. Therefore, the attachment of COOH groups with a reasonable concentration to the MWCNT surface may be an effective way to significantly improve the load transfer between the MWCNT and the ultralight foamed concrete matrix, leading to increased compressive and flexural strength values of composites.

Keywords

• ultralight foamed concrete
• multi-walled carbon nanotube
• interfacial bonding characteristics
• compressive strength
• flexural strength