Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework

Abstract

Gaining molecular-level insight into host–guest binding interactions is fundamentally important, but experimentally challenging. Here, Schröder and co-workers study CO2–host hydrogen bonding interactions in a pair of isostructural redox-active VIII/VIVMOFs using neutron scattering and diffraction techniques.