Manufacturing and Joining PP/NBR Blends in the Presence of Dual Compatibilizer and Halloysite Nanotubes

Abstract

Polypropylene (PP)/acrylonitrile butadiene rubber (NBR) composite plates reinforced with halloysite nanotubes (HNTs) were manufactured in the presence of dual compatibilizers: PP-grafted maleic anhydride (PP-g-MA) and styrene ethylene butylene styrene-grafted maleic anhydride (SEBS-g-MA). The mechanical characteristics and microstructure of the PP/NBR/HNT nanocomposites were investigated as a function of NBR content (10, 20, and 30 wt.%) and HNTs content (3, 5, and 7 wt.%). The results demonstrated that the rubber particles were well dispersed over the PP matrix and that the HNTs were partly agglomerated at contents above 5%. Friction stir welding (FSW) was used to join the nanocomposite plates. A significant reduction in scattered NBR droplet size was seen in the FS-welded specimens containing 80/20 (wt/wt) PP/NBR composites in the presence of a dual compatibilizer. Considerable improvement in particle dispersion was observed in the case of PP/NBR blends filled 80/20 (wt/wt) with HNTs joined using FSW, leading to enhanced mechanical properties in the joints. This was due to the stirring action of the FSW tool. Suitable agreement between anticipated and confirmed values was observed in experiments.

Keywords

• polypropylene (PP)
• halloysite nanotubes (HNTs)
• nanocomposite
• friction stir welding (FSW)
• mechanical properties
• microstructural evaluation