The Application of Electrical Parameters to Reflect the Hydration Process of Cement Paste with Rice Husk Ash

Abstract

This paper aims to study the electrical parameters (electrical resistivity and alternating current (AC) impedance spectroscopy) of cement paste with rice husk ash (RHA). The water to cement (Mass ratio of water to cement (w/c)) ratios of the paste in this study varied from 0.4 to 0.5. The mass ratio of rice husk ash in each w/c ratio of specimens ranged from 0% to 15% by t mass of cement. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to determine the microstructures of specimens. Moreover, the slump flow and plastic viscosity of fresh paste were determined. The results indicated that with the increasing dosage of RHA, the fluidity decreased, while the plastic viscosity increased. Meanwhile, a high w/c ratio led to a low plastic viscosity and high slump flow. The electrical resistivity of RHA cement paste gradually ascended with the increasing curing period. The conduction of specimens intricately changed by mixing RHA, a reasonable equivalent circuit was selected to describe the conduction mechanism by AC impedance spectroscopy. Additionally, the results of XRD and SEM showed that RHA could effectively promote the hydration process as well as decrease the size and number of cracks in hardened cement paste.

Keywords

• electrical resistivity
• AC impedance spectroscopy
• cement paste
• rice husk ash
• equivalent circuit