Molecules (Nov 2022)

Unexpected Room Temperature Ferromagnetism of a Ball-Milled Graphene Oxide—Melamine Mixture

  • Vladimir P. Vasiliev,
  • Eugene N. Kabachkov,
  • Alexander V. Kulikov,
  • Roman A. Manzhos,
  • Iurii G. Morozov,
  • Yury M. Shulga

DOI
https://doi.org/10.3390/molecules27227698
Journal volume & issue
Vol. 27, no. 22
p. 7698

Abstract

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Nitrogen-doped carbon nanomaterial (NDCNM) was synthesized by grinding a mixture of graphene oxide and melamine in a planetary mill with both balls and milling chamber of zirconium dioxide. In the electron spin resonance spectrum of NDCNM, a broad signal with g = 2.08 was observed in addition to a narrow signal at g = 2.0034. In the study using a vibrating-sample magnetometer, the synthesized material is presumably a ferromagnet with a coercive force of 100 Oe. The specific magnetization at 10,000 Oe is approximately 0.020 and 0.055 emu/g at room temperature and liquid nitrogen temperature, respectively.

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