Films of Polyphthalocyanines for Gas Sensitivity Study at Low Temperatures

Abstract

Phthalocyanines and their analogs have practical interest at development devices with low consumption because these materials are known to considerably modify their electrophysical properties on adsorption of the active gases at low temperatures. The conductivity, resistance-temperature relationship, sensor properties relative to NO, O2 and H2S of films based on oligo-(OPc) and polyphthalocyanines (PPc) containing Co, Cu, Fe and Mn were investigated in the present work. Polymeric films were deposited on the test structures with a pair of interdigital metal electrodes. The sensor’s active area was 4.0 × 4.0 mm, and electrode gap was egual 0.08 mm. The sensitive layers were formed by two methods. The soluble OPcs were deposited from their saturated dimethylformamide solutions and insoluble PPcs were deposited by the thermal sputtering in vacuum. The investigations were carried out under the sensor thermal stabilization conditions in the range 50⁻250 °C with the constant values of the heater resistance.

Keywords

• oligophthalocyanine
• polyphthalocyanine
• film
• gas sensor