Keggin-Type Heteropolyacids-Catalyzed One Pot Oxidation-Trimerization of Alcohols into 2,4,6-Trisubstituted-1,3,5-Trioxanes

M. Majid Heravi; Sodeh Sadjadi; Rahim Hekmatshoar; Hossein Abdi Oskooie; Fatemeh Bamoharram

Iranian Journal of Chemistry & Chemical Engineering (Jun 2009)

Keggin-Type Heteropolyacids-Catalyzed One Pot Oxidation-Trimerization of Alcohols into 2,4,6-Trisubstituted-1,3,5-Trioxanes

M. Majid Heravi,
Sodeh Sadjadi,
Rahim Hekmatshoar,
Hossein Abdi Oskooie,
Fatemeh Bamoharram

Affiliations

M. Majid Heravi: Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN
Sodeh Sadjadi: Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN
Rahim Hekmatshoar: Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN
Hossein Abdi Oskooie: Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN
Fatemeh Bamoharram: Department of Chemistry, Islamic Azad University, Mashhad Branch, Mashhad, I.R. IRAN

Journal volume & issue: Vol. 28, no. 2
pp. 131 – 136

Abstract

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The catalytic air oxidation-trimerization of alcohols was carried out with hetropolyacids. In the presence of hetropolyacid formation of cyclotrimers of alcohols and aldol condensation products was observed. The 1,3,5-trioxanes were major and aldol condensation compounds were minor products.

Published in Iranian Journal of Chemistry & Chemical Engineering

ISSN: 1021-9986 (Print)
Publisher: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
Country of publisher: Iran, Islamic Republic of
LCC subjects: Technology: Chemical technology: Chemical engineering; Science: Chemistry
Website: http://www.ijcce.ac.ir

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