Nature Communications (Sep 2021)

Efficient access to aliphatic esters by photocatalyzed alkoxycarbonylation of alkenes with alkyloxalyl chlorides

  • Jian-Qiang Chen,
  • Xiaodong Tu,
  • Qi Tang,
  • Ke Li,
  • Liang Xu,
  • Siyu Wang,
  • Mingjuan Ji,
  • Zhiming Li,
  • Jie Wu

DOI
https://doi.org/10.1038/s41467-021-25628-x
Journal volume & issue
Vol. 12, no. 1
pp. 1 – 15

Abstract

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Aliphatic esters are essential constituents of biologically active compounds but their preparation from readily available olefins remains challenging. Here the authors show a strategy to access aliphatic esters from olefins through a unique photocatalyzed alkoxycarbonylation reaction.