Acta Crystallographica Section E (Oct 2011)

1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one

  • Seik Weng Ng,
  • Edward R. T. Tiekink,
  • Jean M. M. Santos,
  • Carlos R. Cerqueira Jr,
  • Paulo R. Olivato,
  • Julio Zukerman-Schpector

DOI
https://doi.org/10.1107/S1600536811037111
Journal volume & issue
Vol. 67, no. 10
pp. o2759 – o2759

Abstract

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The piperidone ring in the title compound, C20H23NOS2, has a half-chair distorted to a twisted-boat conformation [QT = 0.5200 (17) Å]. One of the S-bound benzene rings is almost perpendicular to the least-squares plane through the piperidone ring, whereas the other is not [dihedral angles = 75.28 (5) and 46.41 (5) Å, respectively]. In the crystal, the presence of C—H...O and C—H...π interactions leads to the formation of supramolecular layers in the ab plane.