Synthesis of ZnO and CuO nanoparticles via Sol gel method and its characterization by using various technique

Abstract

Abstract Nanotechnology is a completely unique branch of technology that offers with substances in a very small size between (1–100 nm) with various crystal shapes. Metals have ability to produce large number of oxides. These metal oxides play a major role in many areas of chemistry, physics, material science and food science. In this research, Zinc Oxide (ZnO) and Copper (II) oxide nanoparticles were synthesized via sol–gel process using zinc nitrate and copper (II) nitrate as precursor respectively. The characterization of CuO and ZnO nanoparticles was done by using various techniques. X-ray Diffraction (XRD) indicates the crystallinity and crystal size of CuO and ZnO nanoparticle. Fourier transform infrared spectroscopy (FT-IR) was used to get the infrared spectrum of the sample indicating composition of the sample which contains various functional groups. XRD result shows the particle size of CuO at highest peak 29.40140 was 61.25 nm and the particle size of ZnO at highest peak 36.2476° was 21.82 nm. FT-IR spectra peak at 594.56 cm-1 indicated characteristic absorption bands of ZnO nanoparticles and the broad band peak at 3506.9 cm−1 can be attributed to the characteristic absorption of O–H group. The analysis of FT-IR spectrum of CuO shows peaks at 602.09, 678.39, and 730.19 cm−1 which refer to the formation of CuO. SEMimages indicate the morphology of CuO and ZnO nanoparticles. Result of EDX characterization indicates that the both synthesized nanoparticles have good purity with very less amount of impurities. EDX data indicates that Cu content was 54.56%, oxygen content was 33.75% in CuO nanoparticles and Zn determined by EDX was 40.77 and O was 45.82 in ZnO. Graphical Abstract

Keywords

• CuO and ZnO Nanoparticles
• XRD
• FT-IR
• SEM
• EDX
• Sol–Gel Method