Acta Crystallographica Section E (Nov 2011)
[N,N-Bis(diphenylphosphanyl)benzylamine-κ2P,P′]dichloridonickel(II) dichloromethane monosolvate
Abstract
In the title solvated complex, [NiCl2(C31H27NP2)]·CH2Cl2, the Ni2+ ion is coordinated by two chloride ions and two P atoms of the chelating N,N-bis(diphenylphosphanyl)benzyl ligand to generate a strongly distorted cis-NiCl2P2 square-planar geometry for the metal ion. In the crystal, the components are linked by C—H...Cl interactions.