Recovery of Lead (II) Ions from Aqueous Solutions Using G-26 and MTS9570 Resins with Sulfonic/Phosphonic Functional Groups

Abstract

This study presents Pb(II) recovery/removal from water solutions using two different commercial ion-exchange resins, i.e., Dowex G-26 with sulfonic functional group and Puromet™ MTS9570 with sulfonic and phosphonic functional groups. Overall, 100% Pb(II) recovery/removal by both resins was obtained at solution pH 3.5, resin dosage 25 g/L, adsorption time 30 min, room temperature, and initial Pb(II) concentration 1000 mg/L. Langmuir, Freundlich, and Temkin isotherms were used to model the experimental data. The mechanism of the adsorption process was investigated using kinetic and thermodynamic models. The experimental data fitted very well with the pseudo-second-order kinetic model, and thermodynamic analysis showed that the adsorption of Pb(II) from acidic solution onto both resins was a spontaneous and endothermic process in nature. Regeneration of the resins loaded with lead ions was tested for three cycles to evaluate the resin recyclability. Good stability of G-26 and performance degradation of MTS9570 resin was observed.

Keywords

• Pb(II)
• ion-exchange resins
• regeneration
• isotherms
• kinetics
• thermodynamics