Nature Communications (Nov 2022)

Regioselective Ni-Catalyzed reductive alkylsilylation of acrylonitrile with unactivated alkyl bromides and chlorosilanes

  • Jinwei Sun,
  • Yongze Zhou,
  • Rui Gu,
  • Xin Li,
  • Ao Liu,
  • Xuan Zhang

DOI
https://doi.org/10.1038/s41467-022-34901-6
Journal volume & issue
Vol. 13, no. 1
pp. 1 – 10

Abstract

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Synthetic methodologies that enable the formation of C‒Si bonds in organic molecules are desirable. Here, the authors report the nickel-catalyzed reductive alkylsilylation of acrylonitrile with unactivated alkyl bromides and chlorosilanes.