Molecules (Mar 1999)

Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6

  • Yong-Zhong Yu,
  • Jian-Guang Sun,
  • Hong Yan,
  • Xiao-Pei Guan

DOI
https://doi.org/10.3390/40300069
Journal volume & issue
Vol. 4, no. 3
pp. 69 – 72

Abstract

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Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane (1) with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H,5H-diimidazolinium[4,5-b:4',5'-e]pyrazine dinitrate (2).

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