Research Progress in Strategies for Enhancing the Conductivity and Conductive Mechanism of LiFePO₄ Cathode Materials

Abstract

LiFePO4 is a cathode material for lithium (Li)-ion batteries known for its excellent performance. However, compared with layered oxides and other ternary Li-ion battery materials, LiFePO4 cathode material exhibits low electronic conductivity due to its structural limitations. This limitation significantly impacts the charge/discharge rates and practical applications of LiFePO4. This paper reviews recent advancements in strategies aimed at enhancing the electronic conductivity of LiFePO4. Efficient strategies with a sound theoretical basis, such as in-situ carbon coating, the establishment of multi-dimensional conductive networks, and ion doping, are discussed. Theoretical frameworks underlying the conductivity enhancement post-modification are summarized and analyzed. Finally, future development trends and research directions in carbon coating and doping are anticipated.

Keywords

• lithium iron phosphate
• conductivity
• carbon coating
• doping