Metals (May 2022)

Synthesis of Weyl Semi-Metal Co<sub>3</sub>Sn<sub>2</sub>S<sub>2</sub> by Hydrothermal Method and Its Physical Properties

  • Guifeng Chen,
  • Bolin Long,
  • Lei Jin,
  • Hui Zhang,
  • Zishuang Cheng,
  • Xiaoming Zhang,
  • Guodong Liu

DOI
https://doi.org/10.3390/met12050830
Journal volume & issue
Vol. 12, no. 5
p. 830

Abstract

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In the field of condensed matter physics, as new quantum materials, topological semimetals have a special topological energy band structure and nontrivial band crossings in the energy band, which will have many excellent topological properties, such as internal insulation of topological insulators and the presence of conduction electrons on the surface; this makes topological semimetals exhibit wider application prospects in electronic devices. So far, the experimental synthesis of topological semimetals was performed using physical methods to synthesize bulk single crystals, which is not conducive to the commercial application of micro and small devices. Weyl semimetal Co3Sn2S2 with shandite structure was successfully synthesized experimentally by a green and environmentally friendly hydrothermal method. Adjusting its reaction temperature, molar atomic ratio of elements and annealing temperature, and other experimental conditions, we analyze the crystal structure and physical properties of Co3Sn2S2, with the nanocrystal size being about 200 nm. We found that the Co3Sn2S2 synthesized by the hydrothermal method has a Curie temperature at 100 K to undergo ferromagnetic transition.

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