Thermal Evaluation of a Novel Integrated System Based on Solid Oxide Fuel Cells and Combined Heat and Power Production Using Ammonia as Fuel

Abstract

A novel integrated system based on solid oxide fuel cells (SOFCs), a gas turbine (GT), the steam Rankine cycle (SRC), the Kalina cycle (KC), and the organic Rankine cycle (ORC) is proposed to achieve cascade energy utilization. Mathematical models are introduced and system performance is analyzed using energy and exergy methods. The first and second laws of thermodynamics are used to analyze the system thermodynamically. In addition, exergy destruction and losses of the various integrated subsystems are calculated. The energy and exergy efficiencies of the multigeneration system are estimated to be 60.4% and 57.3%, respectively. In addition, the hot water produced during the waste heat recovery process may also be used for accommodating seafarers on ships. Sequential optimization is developed to optimize the operating conditions of the integrated system to achieve the required power output. A comprehensive parametric study is conducted to investigate the effect of varying the current densities of the fuel cell and working fluid of the ORC on the overall performance of the combined system and subsystems. The working performance of five working fluids for the ORC as candidates—R134a, R600, R601, R152a, and R124—is compared. R152a, which provides 71.23 kW of power output, and energy and exergy efficiencies of 22.49% and 42.76%, respectively, is selected as the best thermodynamic performance for the ORC.

Keywords

• SOFC
• ammonia
• combine heat and power
• organic Rankine cycle system