Molecules (Feb 2023)

A Stable PDLC Film with High Ageing Resistance from an Optimized System Containing Rigid Monomer

  • Hongren Chen,
  • Xiao Wang,
  • Jianjun Xu,
  • Wei Hu,
  • Meina Yu,
  • Lanying Zhang,
  • Yong Jiang,
  • Huai Yang

DOI
https://doi.org/10.3390/molecules28041887
Journal volume & issue
Vol. 28, no. 4
p. 1887

Abstract

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With the switchability between transparent and light-scattering states, polymer-dispersed liquid crystals (PDLC) are widely used as smart windows, flexible display devices, projectors, and other devices. In outdoor applications, in addition to excellent electro-optical properties, there is also a high demand for film stability. In this work, a PDLC film with high mechanical strength and structural stability is prepared that can maintain stability at 80 °C for 2000 h. By choosing liquid crystals with a wide temperature range, adopting acrylate polymer monomers containing hydroxyl groups, and adjusting the polymer content, the PDLC film can work well from −20 °C to 80 °C. On this basis, the effects of the introduction of rigid monomers on the mechanical properties and electro-optical properties of PDLC films are investigated.

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