Materials & Design (Oct 2022)

Electromagnetic wave-absorbing behavior of soft-magnetic medium entropy alloys with BCC/L21 coherent microstructure

  • Zhiyao Ji,
  • Qing Wang,
  • Zhenhua Wang,
  • Yuping Duan,
  • Chuang Dong,
  • Peter K. Liaw

Journal volume & issue
Vol. 222
p. 111054

Abstract

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Magnetic alloy powders show a great superiority in the balance of permittivity and permeability for electromagnetic (EM) wave-absorption. However, it is necessary to enhance their effective absorption bandwidth (Δf) and impedance matching due to their insufficient soft-magnetic properties and low resistivity, which would be solved by high/medium-entropy alloys (HEAs/MEAs). In this report, we designed Al1.5Co3.5Fe3.5 and Al1.5Co3Fe3Cr MEAs with prominent soft-magnetic property and high resistivity. It is contributed to the special coherent microstructure with ultrafine magnetic body-centered-cubic nanoprecipitates uniformly-distributed into the L21 matrix, which could not be changed by ball-milling. Thus, alloy powders possess excellent EM properties, as evidenced by the minimum reflection loss of −42.2 dB at 14.52 GHz and the largest Δf = 7.01 GHz in 5 h-milled Al1.5Co3.5Fe3.5, better than existing alloy powders. The wave-absorbing behavior of MEA powders was discussed from both permittivity and permeability. The current findings offer a useful design strategy for developing high-performance absorbers.

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