Acta Crystallographica Section E (Jun 2014)

Methyl (E)-3-(2-formylphenoxy)acrylate

  • S. Karthikeyan,
  • K. Sethusankar,
  • R. Selvakumar,
  • M. Bakthadoss

DOI
https://doi.org/10.1107/S1600536814010617
Journal volume & issue
Vol. 70, no. 6
pp. o709 – o709

Abstract

Read online

In the title compound, C11H10O4, the methyl acrylate substituent adopts an extended E conformation with all torsion angles close to 180°. The conformation of the keto group with respect to the olefinic double bond is typically S-trans. In the crystal, molecules are linked via pairs of C—H...O hydrogen bonds, forming inversion dimers with an R22(8) graph-set motif. The dimers are further linked via C—H...O hydrogen bonds, forming chains along [001], which enclose R32(16) graph-set ring motifs. The keto group O atomaccepts two C—H...O interactions.