Nanomaterials (Jan 2022)

In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol

  • Lauriane Bruna,
  • Miquel Cardona-Farreny,
  • Vincent Colliere,
  • Karine Philippot,
  • M. Rosa Axet

DOI
https://doi.org/10.3390/nano12030328
Journal volume & issue
Vol. 12, no. 3
p. 328

Abstract

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Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hydrogenation/C-O cleavage procedure. Colloidal ruthenium nanoparticles stabilized with polyvinylpyrrolidone in situ modified with different organic compounds are able to produce 1,2-pentanediol directly from furfural in a 36% of selectivity at 125 °C under 20 bar of H2 pressure.

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