Frontiers in Chemistry (May 2022)

Supported Palladium Nanoparticles Catalyzed Intermolecular Carbopalladation of Nitriles and Organoboron Compounds

  • Xin Liu,
  • Dan Liu,
  • Tegshi Muschin,
  • Agula Bao,
  • Chaolumen Bai,
  • Yong-Sheng Bao

DOI
https://doi.org/10.3389/fchem.2022.855850
Journal volume & issue
Vol. 10

Abstract

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The first heterogeneous catalyzed example for the direct synthesis of aromatic ketones via intermolecular carbopalladation of aliphatic nitriles and organoboron compounds was developed. This mild method proceeds with a supported palladium nanoparticles catalyst that could be reused and recycled five times. The fresh and used catalysts were characterized by XPS and TEM. The XPS analysis indicated that Pd0 was the active species for the reaction. This methodology provides a mild and cost-effective strategy for the efficient synthesis of ketones.

Keywords