ROLE OF Mn(TPP)Cl IN THE EPOXIDATION
WITH SINGLET OXYGEN

Journal of Sciences, Islamic Republic of Iran (Mar 2000)

ROLE OF Mn(TPP)Cl IN THE EPOXIDATION WITH SINGLET OXYGEN

Journal volume & issue: Vol. 11, no. 1

Abstract

Mn(TPP)Cl catalyzes cooxidation of olefin in the singlet oxygenation of sulfid. Mn(TPP)Cl is able to transfer an oxygen atom from a peroxidic intermediate generated in singlet oxygenation of sulfide to a metal ion affording metal 0x0 species which is responsible for epoxidation. This system leads to allcenes epoxidation such as styrene and cyclooctene. Epoxidation of cyclohexene produces cyclohexenol, cyclohexenone and cyclohexene oxide

Published in Journal of Sciences, Islamic Republic of Iran

ISSN: 1016-1104 (Print); 2345-6914 (Online)
Publisher: University of Tehran
Country of publisher: Iran, Islamic Republic of
LCC subjects: Science
Website: https://jsciences.ut.ac.ir/

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