Acta Crystallographica Section E (Jul 2013)

2-{(E)-[(2-Methyl-3-nitrophenyl)imino]methyl}-4-nitrophenol

  • Hasan Tanak,
  • Ferhat Toğurman,
  • Sedanur Kalecik,
  • Necmi Dege,
  • Metin Yavuz

DOI
https://doi.org/10.1107/S1600536813015407
Journal volume & issue
Vol. 69, no. 7
pp. o1085 – o1085

Abstract

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The title compound, C14H11N3O5, is a Schiff base that adopts the enol–imine tautomeric form in the solid state. The dihedral angle between the aromatic rings is 37.4 (3)° and the dihedral angles between the nitro groups and their attached rings are 4.0 (6) and 46.2 (8)°. The molecular structure is stabilized by an intramolecular O—H...N hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked by C—H...O interactions, forming a two-dimensional network parallel to the bc plane.