Hydronitrogen Molecular Assisted Recombination (HN-MAR) process in ammonia seeded deuterium plasmas

Abstract

Ammonia molecules, which will be formed in a nitrogen-seeded divertor plasma, show significant catalytic effects for volumetric recombination of hydrogen ions. This new Molecular Assisted Recombination (MAR), named the Hydronitrogen-MAR (HN-MAR), is based on the charge/ion exchange with NH3 and subsequent volumetric recombination of NH3+ and NH4+. In our PISCES-E RF plasma device, Ar is mixed with ND3/D2 gasses to realize a high electron density plasma [ne ∼ 1017 m−3] which allows us to see the importance of the dissociative recombination reactions which become comparable with wall loss reactions in our chamber. As increasing the plasma density, a calibrated Electrostatic Quadrupole Plasma analyzer measured dropping of ND4+ density fractions which can be explained reasonably by the existence of its dissociative recombination process in the plasma as a dominant reaction. Keywords: Ammonia, MAR, Detachment, Charge exchange, Recombination, Combined ion mass and energy analyzer