First Total Synthesis of Artekeiskeanol A, C and Altissimacoumarin D

Abstract

Abstract The total syntheses of artekeiskeanol A and C, and altissimacoumarin D have been achieved. The syntheses commenced from commercially available starting materials, 2,4-dihydroxybenzaldehyde and geraniol. The key steps involve Wittig and Riley oxidation reactions.

Keywords

• geronyl
• scopoletin
• isofraxidin
• altissimacoumarin
• artekeiskeanol